JEE Main 2019 — D And F Block Elements Question with Solution
From: JEE Main 2019 (Online) 10th April Morning Slot
Question
Consider the hydrated ions of Ti2+, V2+, Ti3+, and Sc3+. The correct order of their spin-only magnetic
moments is :
Choose an option
Show full solutionCorrect option: B
Correct answer
BSc3+ < Ti3+ < Ti2+ < V2+
Step-by-step explanation
As we know that
where n = no. of unpaired electrons i.e. greater the no. of unpaired electron more will be the spin-only magnetic moments.
. Electronic configuration of the given transition metal ions are
Sc3+ (Z = 21) = 1s22s22p63s23p6
n = 0
Ti2+ (Z = 22) = 1s22s22p63s23p63d2
n = 2
Ti3+ (Z = 22) = 1s22s22p63s23p63d1
n = 1
V2+ (Z = 23) = 1s22s22p63s23p63d3
n = 3
So the correct increasing order of magnetic moment is
Sc3+ < Ti3+ < Ti2+ < V2+
where n = no. of unpaired electrons i.e. greater the no. of unpaired electron more will be the spin-only magnetic moments.
. Electronic configuration of the given transition metal ions are
Sc3+ (Z = 21) = 1s22s22p63s23p6
n = 0
Ti2+ (Z = 22) = 1s22s22p63s23p63d2
n = 2
Ti3+ (Z = 22) = 1s22s22p63s23p63d1
n = 1
V2+ (Z = 23) = 1s22s22p63s23p63d3
n = 3
So the correct increasing order of magnetic moment is
Sc3+ < Ti3+ < Ti2+ < V2+
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