JEE Main 2025ChemistryStructure Of AtomQuantum Numbers And OrbitalseasyMCQ

JEE Main 2025Structure Of Atom Question with Solution

From: JEE Main 2025 (Online) 7th April Evening Shift

Question

The extra stability of half-filled subshell is due to :

(A) Symmetrical distribution of electrons

(B) Smaller coulombic repulsion energy

(C) The presence of electrons with the same spin in non-degenerate orbitals

(D) Larger exchange energy

(E) Relatively smaller shielding of electrons by one another

Indentify the correct statements :

Choose an option

Show full solutionCorrect option: B
Correct answer
B and (E) only

Step-by-step explanation

The enhanced stability of a half-filled subshell is attributed to the following factors:

Symmetrical Distribution of Electrons: Electrons are evenly distributed across the available orbitals, leading to a balanced and stable arrangement.

Large Exchange Energy: The energy due to the exchange of electrons with parallel spins among degenerate orbitals is maximized, contributing to increased stability.

Smaller Coulombic Repulsion: The repulsion between electrons is minimized in a half-filled configuration, reducing the overall energy of the subshell.

Smaller Shielding of Electrons: In a half-filled subshell, electrons are more exposed to the nuclear charge, as there is less shielding effect from other electrons, enhancing stability.

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About this question

This is a previous-year question from JEE Main 2025, covering the Structure Of Atom chapter of Chemistry. PrepSharp catalogues every PYQ from JEE Main with a verified answer key and step-by-step solution prepared by IIT alumni — so you can search by chapter, topic or year and revise efficiently.