JEE Main 2021 — Salt Analysis Question with Solution
From: JEE Main 2021 (Online) 25th February Evening Shift
Question
Statement I : The identification of Ni2+ is carried out by dimethyl glyoxime in the presence of NH4OH.
Statement II : The dimethyl glyoxime is a bidentate neutral ligand.
In the light of the above statements, choose the correct answer from the options given below :
Choose an option
Show full solutionCorrect option: D
Step-by-step explanation
Statement I is true. Dimethyl glyoxime (DMG) is a chelating reagent commonly used for the identification of Ni2+ ions in aqueous solution. In the presence of ammonium hydroxide (NH4OH), Ni2+ reacts with dimethyl glyoxime to form a deep red-colored complex, which can be used to confirm the presence of Ni2+ ions.
Statement II is also true. Dimethyl glyoxime is a neutral bidentate ligand, which means it has two donor atoms that can coordinate with a metal ion, and its overall charge is neutral.

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