JEE Main 2023ChemistryPolymersClassification Preparations And Properties Of PolymersmediumMCQ

JEE Main 2023Polymers Question with Solution

From: JEE Main 2023 (Online) 11th April Evening Shift

Question

Given below are two statements :

Statement I : Ethene at 333 to and - atm pressure in the presence of and undergoes addition polymerization to give LDP.

Statement II : Caprolactam at - in through step growth polymerizes to give Nylon 6.

In the light of the above statements, choose the correct answer from the options given below:

Choose an option

Show full solutionCorrect option: C
Correct answer
CStatement I is false but Statement II is true

Step-by-step explanation

Statement I is false. Ethene (ethylene) under certain conditions (high pressure, high temperature) in the presence of catalysts does undergo addition polymerization, but it forms polyethylene, not LDP (Low-Density Polyethylene) specifically. The formation of low-density polyethylene (LDPE) vs high-density polyethylene (HDPE) depends on the specific conditions and catalysts used. The catalysts mentioned (AlEt3 and TiCl4) are associated with the production of HDPE through the Ziegler-Natta process, not LDPE.

Statement II is true. Caprolactam polymerizes to form Nylon 6 via a ring-opening polymerization mechanism, which is a type of step-growth polymerization. The process is often carried out at high temperatures, and water is a byproduct of the reaction, so the description in Statement II is accurate.

Therefore, Option C (Statement I is false but Statement II is true) is the correct answer.

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About this question

This is a previous-year question from JEE Main 2023, covering the Polymers chapter of Chemistry. PrepSharp catalogues every PYQ from JEE Main with a verified answer key and step-by-step solution prepared by IIT alumni — so you can search by chapter, topic or year and revise efficiently.