JEE Main 2021ChemistryIonic EquilibriumPh Buffer And IndicatorsmediumMCQ

JEE Main 2021Ionic Equilibrium Question with Solution

From: JEE Main 2021 (Online) 26th August Morning Shift

Question

Given below are two statements.

Statement I : In the titration between strong acid and weak base methyl orange is suitable as an indicator.

Statement II : For titration of acetic acid with NaOH phenolphthalein is not a suitable indicator.

In the light of the above statements, choose the most appropriate answer from the options given below :

Choose an option

Show full solutionCorrect option: B
Correct answer
BStatement I is true but Statement II is false

Step-by-step explanation

Titration curve for strong acid and weak base initially a buffer of weak base and conjugate acid is :

JEE Main 2021 (Online) 26th August Morning Shift Chemistry - Ionic Equilibrium Question 61 English Explanation 1

Formed, thus pH falls slowly and after equivalence point, so the pH falls sharply so methyl orange, having pH range of 3.2 to 4.4 will weak as indicator. So, statement I is correct.

JEE Main 2021 (Online) 26th August Morning Shift Chemistry - Ionic Equilibrium Question 61 English Explanation 2

Titration curve for weak acid and strong base (NaOH)

Initially weak acid will form a buffer so pH increases slowly but after equivalence point. It rises sharply covering range of phenolphthalein so it will be suitable indicator so statement II is false.

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About this question

This is a previous-year question from JEE Main 2021, covering the Ionic Equilibrium chapter of Chemistry. PrepSharp catalogues every PYQ from JEE Main with a verified answer key and step-by-step solution prepared by IIT alumni — so you can search by chapter, topic or year and revise efficiently.