JEE Main 2025ChemistryHydrocarbonsAromatic HydrocarbonshardNumerical

JEE Main 2025Hydrocarbons Question with Solution

From: JEE Main 2025 (Online) 29th January Evening Shift

Question

Isomeric hydrocarbons → negative Baeyer’s test

(Molecular formula C9H12)

The total number of isomers from above with four different non-aliphatic substitution sites is -

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Step-by-step explanation

Molecular formula of isomeric hydrocarbon - Negative Baeyer's test

Baeyers test is given by compounds that contain readily active carbon-carbon double bond.

So, in a negative Baeyer's test, there is no readily active c = c.

Compounds that give negative Baeyer's test are alkanes and aromatic compounds.

CH compound is not an alkane

(Alkane general formula CH)

Hydrocarbons with the formula CH are considered as aromatic and isomers of substituted benzene rings.

The possible isomers of CH are

JEE Main 2025 (Online) 29th January Evening Shift Chemistry - Hydrocarbons Question 17 English Explanation 1

From these, total number of the isomers with four different non-aliphatic substitution sites are 2

JEE Main 2025 (Online) 29th January Evening Shift Chemistry - Hydrocarbons Question 17 English Explanation 2 JEE Main 2025 (Online) 29th January Evening Shift Chemistry - Hydrocarbons Question 17 English Explanation 3 JEE Main 2025 (Online) 29th January Evening Shift Chemistry - Hydrocarbons Question 17 English Explanation 4
Four positions (1,2,3,4) are different. So, it contain four different non-aliphatic substitution sites. Four position (1,2,3,4) are different. So, it contain four different non-aliphatic substitution sites. Four position (1,2,3,4) are not different. So, it contain four different non-aliphatic substitution sites.

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About this question

This is a previous-year question from JEE Main 2025, covering the Hydrocarbons chapter of Chemistry. PrepSharp catalogues every PYQ from JEE Main with a verified answer key and step-by-step solution prepared by IIT alumni — so you can search by chapter, topic or year and revise efficiently.