JEE Main 2019ChemistryCoordination CompoundsCrystal Field Theory CfthardMCQ
JEE Main 2019 — Coordination Compounds Question with Solution
From: JEE Main 2019 (Online) 12th April Morning Slot
Question
The complex ion that will lose its crystal field stabilization energy upon oxidation of its metal to +3 state is :
This question includes a diagram. The text above accompanies the figure.
Choose an option
▸Show full solutionCorrect option: A
Correct answer
A[Fe(phen)3]2+
Step-by-step explanation
[Fe(phen)3]2+→ [Fe(phen)3]3+
Here for Fe+2(3d6) :
CFSE = (-0.4 × 4 + 0.6 × 2)Δ0
= -0.4Δ0
for Fe+3(3d5) :
CFSE = (-0.4 × 3 + 0.6 × 2)Δ0
= 0
Here crystal field stabilization energy(CFSE) decreses.
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