JEE Main 2019ChemistryCoordination CompoundsMediumMCQ

JEE Main 2019Coordination Compounds Question with Solution

JEE Main 2019 (10 Jan Shift 2)

Question

A reaction of cobalt (III) chloride and ethylenediamine in a 1 : 2 mole ratio generates two isomeric products A (violet-coloured) and B (green-coloured). A can show optical activity, but, B is optically inactive. What type of isomers do A and B represent?

Choose an option

Show full solutionCorrect option: D
Correct answer
DGeometrical isomers

Step-by-step explanation

The coordination number of cobalt is 6.

The mole ratio of CoCl3 and en is 1 : 2.

Hence,

CoCl3+2 enCoen2Cl2 Cl

The complex formed shows geometrical isomerism.

The complex exists as cis and trans isomers among which the trans isomer is optically inactive.

 

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About this question

This is a previous-year question from JEE Main 2019, covering the Coordination Compounds chapter of Chemistry. PrepSharp catalogues every PYQ from JEE Main with a verified answer key and step-by-step solution prepared by IIT alumni — so you can search by chapter, topic or year and revise efficiently.