JEE Main 2020 — Amines Question with Solution

The basic nature of amines can be explained on the basis hybridisation. The basic nature order is ${\mathrm{sp}}^3>{\mathrm{sp}}^2>\mathrm{sp}$. If the lone pair on nitrogen involved in resonance, then it is less basic than others. In the molecules A, B and D, the nitrogen is ${\mathrm{sp}}^2$ hybridised. In the pyrrole molecule the lone pair on nitrogen involving in conjugation to get aromaticity. Hence, C is most basic and B is least basic.