JEE Main 2016ChemistryAminesMediumMCQ

JEE Main 2016Amines Question with Solution

JEE Main 2016 (09 Apr Online)

Question

The test to distinguish primary, secondary and tertiary amines is:

Choose an option

Show full solutionCorrect option: D
Correct answer
DC6H5SO2Cl

Step-by-step explanation

The Hinsberg test, which can distinguish primary, secondary, and tertiary amines, is based upon sulfonamide formation. In the Hinsberg test, an amine is reacted with benzene sulfonyl chloride. If a product forms, the amine is either a primary or secondary amine, because tertiary amines do not form stable sulfonamides. If the sulfonamide that forms dissolves in aqueous sodium hydroxide solution, it is a primary amine. If the sulfonamide is insoluble in aqueous sodium hydroxide, it is a secondary amine

Benzene sulphonyl chloride is Hinsberg reagent.

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About this question

This is a previous-year question from JEE Main 2016, covering the Amines chapter of Chemistry. PrepSharp catalogues every PYQ from JEE Main with a verified answer key and step-by-step solution prepared by IIT alumni — so you can search by chapter, topic or year and revise efficiently.