JEE Main 2012ChemistryAlcohols Phenols And EthersProperties Preparation And Uses Of PhenolseasyMCQ

JEE Main 2012Alcohols Phenols And Ethers Question with Solution

From: AIEEE 2012

Question

Ortho–Nitrophenol is less soluble in water than p– and m– Nitrophenols because :

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Show full solutionCorrect option: B
Correct answer
Bo–Nitrophenol shows Intramolecular H–bonding

Step-by-step explanation

As in ortho-Nitrophenol H of -OH is already in Intra-moleculer H Bond and become stable so it will not perticipate in H bonding with H2O by breaking this H bonding. That is why solublity of Ortho–Nitrophenol is less in water. AIEEE 2012 Chemistry - Alcohols, Phenols and Ethers Question 169 English Explanation 1

para– and meta– Nitrophenols both shows inter-moleculer H bonding with H2O. That is why both are more soluble in water. AIEEE 2012 Chemistry - Alcohols, Phenols and Ethers Question 169 English Explanation 2 AIEEE 2012 Chemistry - Alcohols, Phenols and Ethers Question 169 English Explanation 3

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About this question

This is a previous-year question from JEE Main 2012, covering the Alcohols Phenols And Ethers chapter of Chemistry. PrepSharp catalogues every PYQ from JEE Main with a verified answer key and step-by-step solution prepared by IIT alumni — so you can search by chapter, topic or year and revise efficiently.